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The article, machinery, or apparatus, if unpackaged, or the packaging in which it is contained shall be marked Dangerous goods in articles or Dangerous goods in machinery or Dangerous goods in apparatus as appropriate, with the identification number UN3363. will bring you directly to the content. Except for transportation by aircraft, in palletized loads, a pallet box or unit load device (e.g. In addition, for solid materials, special provision B54 applies. 47 Mixtures of solids that are not subject to this subchapter and flammable liquids may be transported under this entry without first applying the classification criteria of Division 4.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Examples of equipment are lawnmowers, cleaning machines, or model boats and model aircraft. 385 Notwithstanding the provisions of 177.834(l) of this subchapter, cargo heaters may be used when weather conditions are such that the freezing of a wetted explosive material is likely. Special Provision Letter Codes Used in Hazmat Table, Column 7 Column 7 uses eight letter codes. Insulation must be at least 100 mm (3.9 inches) except that the insulation thickness may be reduced to 51 mm (2 inches) over the exterior heater coils. The HMT provides the basic information necessary to ship a hazardous material safely. Lighter refills offered for transportation under this entry may not exceed 4 fluid ounces capacity (7.22 cubic inches) or contain more than 65 grams of fuel. ); and. Compressed air containing greater than 23.5 percent oxygen must be shipped using the description Compressed gas, oxidizing, n.o.s., UN3156.. (2) A codes. These entries include hybrid electric vehicles powered by a fuel cell engine, an internal combustion engine, and batteries. The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage. 336 The use of UN1H1 drums, UN3H1 jerricans, and UN6HA1 composite packagings which meet the requirements of part 178 of the HMR at the Packing Group I or II performance level. 109 Rocket motors must be nonpropulsive in transportation unless approved in accordance with 173.56 of this subchapter. b. 389 This entry only applies to lithium ion batteries or lithium metal batteries installed in a cargo transport unit and designed only to provide power external to the cargo transport unit. This includes hybrid electric vehicles powered by a fuel cell, an internal combustion engine, and wet, sodium or lithium batteries installed. The device must be in the vapor space when the tank is filled under maximum filling conditions. 371 a. 353 Ammonium permanganate, ammonium permanganate aqueous solutions, and mixtures of a permanganate with an ammonium salt are forbidden for transport. In addition to the packaging required in 173.4a, each glass inner packaging must be placed in a sealed plastic bag compatible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner packaging; and. Using the nominal capacitance (CN), rated voltage (UR) and the rated lower limit voltage (UL). 176 This entry must be used for formaldehyde solutions containing methanol as a stabilizer. c. The completed package must meet the Packing Group II performance level, as applicable for combination packagings with a plastic box outer packaging, in accordance with subpart M of part 178 of this subchapter. 6. Except for a portable tank containing refrigerated liquefied helium, a portable tank shall have an outage of at least two percent below the inlet of the pressure relief device or pressure control valve, under conditions of incipient opening, with the portable tank in a level attitude. Alcoholic beverages containing more than 24 percent but not more than 70 percent alcohol by volume must be transported as materials in Packing Group III. TP21 The wall thickness must not be less than 8 mm. When a special provision specifies packaging or packaging requirements -, (1) The special provision is in addition to the standard requirements for all packagings prescribed in 173.24 of this subchapter and any other applicable packaging requirements in subparts A and B of part 173 of this subchapter; and. When a consignment is undeliverable, the consignment shall be placed in a safe location and the appropriate competent authority shall be informed as soon as possible and a request made for instructions on further action. 430 This entry shall only be used for solid medical waste of Category A transported for disposal. Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to the requirements of this subchapter. 2 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone B (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. 347 Effective July 1, 2011, for transportation by aircraft, this entry may only be used if the results of Test series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. When Column 7 refers to a special provision for a hazardous material, the meaning and requirements of that special provision are as set forth in 172.102 of this subpart. 372 This entry applies to asymmetric capacitors with an energy storage capacity greater than 0.3 Wh. 49 CFR 172.101 here. These provisions can be classified even further with each form of transportation. Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. However, button cell batteries installed in equipment (including circuit boards) need not be considered; and, c. The shipping paper must indicate UN 3091 Lithium metal batteries packed with equipment or UN 3481 Lithium ion batteries packed with equipment, as appropriate. Column 1 uses six symbols to identify hazardous materials with special shipping conditions such as restrictions for air, domestic, international, or water vessel transport. 128 Regardless of the provisions of 172.101(c)(12), aluminum smelting by-products and aluminum remelting by-products described under this entry, meeting the definition of Class 8, Packing Group II and III may be classed as a Division 4.3 material and transported under this entry. (i) Tests must be performed on each type and size of bottle, for each manufacturing location. N41 Metal construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. Unfortunately, the amendments to the table entries for various hazardous materials introduced new unintended errors that PHMSA is correcting in this notice. TP33 The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Size of marking on bulk package must conform to 172.302(b) of this subchapter. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. There you have it! For non-pressurized lighters containing a Class 3 (flammable liquid) material, its design, description, and packaging must be approved by the Associate Administrator prior to being offered for transportation or transported in commerce. A112 Notwithstanding the quantity limits shown in Column (9A) and (9B) for this entry, the following IBCs are authorized for transportation aboard passenger and cargo-only aircraft. 342 Glass inner packagings (such as ampoules or capsules) intended only for use in sterilization devices, when containing less than 30 mL of ethylene oxide per inner packaging with not more than 300 mL per outer packaging, may be transported in accordance with 173.4a of this subchapter, irrespective of the restriction of 173.4a(b) and the indication of forbidden in columns (9A) and (9B) of the 172.101 table provided that: a. (iv) The name or symbol of the bottle producer, and the month and year of manufacture, must be marked by embossing, ink-jet printing of permanent ink, or other permanent means on the face or bottom of each bottle, in letters and numbers at least 6 mm (0.2 inch) high. Where the subsidiary hazard material is Forbidden in column (9A) or (9B) of the 172.101 Table, the radioactive material may only be offered for transportation and transported by aircraft under conditions approved by the Associate Administrator. 44 The formulation must be prepared so that it remains homogenous and does not separate during transport. Batteries and battery-powered device(s) containing batteries must be prepared and packaged for transport in a manner to prevent: (2) Short circuits, including but not limited to the following methods: (i) Packaging each battery or each battery-powered device when practicable, in fully enclosed inner packagings made of non-conductive material; (ii) Separating or packaging batteries in a manner to prevent contact with other batteries, devices or conductive materials (e.g., metal) in the packagings; or, (iii) Ensuring exposed terminals or connectors are protected with non-conductive caps, non-conductive tape, or by other appropriate means; and. For example, nickel-metal hydride batteries transported by vessel in certain quantities are covered by another entry (see Batteries, nickel-metal hydride, UN3496). 156 Asbestos that is immersed or fixed in a natural or artificial binder material, such as cement, plastic, asphalt, resins or mineral ore, or contained in manufactured products is not subject to the requirements of this subchapter. Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. Net weight of contents may not exceed 15 kg (33 pounds). Packages containing mixtures with not less than 90% by mass, of phlegmatizer need not bear a POISON subsidiary risk label. It may not be used to describe articles, machinery, or apparatus for which a proper shipping name exists in the 172.101 Table. 335 Mixtures of solids that are not subject to this subchapter and environmentally hazardous liquids or solids may be classified as Environmentally hazardous substances, solid, n.o.s, UN3077 and may be transported under this entry, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Have accident damage protection which conforms with 178.345-8 of this subchapter; c. Have a MAWP or design pressure of at least 87 psig: and. TP7 The vapor space must be purged of air by nitrogen or other means. Use the above summary to assist you in reviewing the special provisions applicable to the HazMat you offer for transportation. 56 A means to interrupt and prevent detonation of the detonator from initiating the detonating cord must be installed between each electric detonator and the detonating cord ends of the jet perforating guns before the charged jet perforating guns are offered for transportation. B11 Tank car tanks must have a test pressure of at least 2,068.5 kPa (300 psig). These provisions apply only to transportation by rail. Essentially, such SSolder complies with RoHS (Restriction of Hazardous Substances) regulations. N8 Nitroglycerin solution in alcohol may be transported under this entry only when the solution is packed in metal cans of not more than 1 L capacity each, overpacked in a wooden box containing not more than 5 L. Metal cans must be completely surrounded with absorbent cushioning material. The in-page Table of Contents is available only when multiple sections are being viewed. (iii) T50 When portable tank instruction T50 is indicated in Column (7) of the 172.101 Hazardous Materials Table, the applicable liquefied compressed gas and chemical under pressure descriptions are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. 115 Boosters with detonator, detonator assemblies and boosters with detonators in which the total explosive charge per unit does not exceed 25 g, and which will not mass detonate and undergo only limited propagation in the shipping package may be assigned to 1.4B classification code. TP46 Portable tanks in sodium metal service are not required to be hydrostatically retested. For transportation by aircraft, as an inner packaging of a combination packaging with a maximum gross mass of 30 kg when packaged as a limited quantity in accordance with 173.27(f). 349 Mixtures of hypochlorite with an ammonium salt are forbidden for transport. These provisions apply only to non-bulk packagings: N3 Glass inner packagings are permitted in combination or composite packagings only if the hazardous material is free from hydrofluoric acid. W100 Non-bulk flexible, fibreboard or wooden packagings must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. IBCs must be packed in closed freight containers or a closed transport vehicle. When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code - or codes, there may be several of them - is in addition to the general packaging requirements of 173.24 and any other applicable packaging requirements in Part 173. The letter Z shown in the marking code for composite IBCs must be replaced with a capital code letter designation found in 178.702(a)(2) of this subchapter to specify the material used for the other packaging. Energy storage capacity means the energy stored in a capacitor, as calculated according to the following equation. (a) General. The eCFR is displayed with paragraphs split and indented to follow Each inner packaging is contained in a sealed leak-proof intermediate packaging with sufficient absorbent material capable of containing the contents of the inner packaging; c. Intermediate packagings are securely packed in an outer packaging of a type permitted by 173.158(g) of this subchapter which meet the requirements of part 178 of this subchapter at the Packing Group I performance level; d. The maximum quantity of nitric acid in the package does not exceed 300 mL; and. A19 Combination packagings consisting of outer fiber drums or plywood drums, with inner plastic packagings, are not authorized for transportation by aircraft. 48 Mixtures of solids that are not subject to this subchapter and toxic liquids may be transported under this entry without first applying the classification criteria of Division 6.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. Explosives shipped in conformance with this paragraph must have been examined in accordance with 173.56 of this subchapter and approved by the Associate Administrator. Non-specification bulk bins are authorized. The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b. 352 Ammonium chlorite, ammonium chlorite aqueous solutions, and mixtures of a chlorite with an ammonium salt are forbidden for transport. All successfully conducted tests or reassignment to another compatibility group require the issuance of a new or revised approval by the Associate Administrator prior to transportation on or after the dates specified for each authorized mode of transport in this special provision. The requirements of 173.24(g)(1) and 173.27(c) do not apply. When chemical stabilization is employed, the person offering the material for transport shall ensure that the level of stabilization is sufficient to prevent the material as packaged from dangerous polymerization at 50 C (122 F). Unlined tanks must be passivated before being placed in service. 163 Substances must satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see 171.7 of this subchapter). These batteries are typically used for portable power applications. This particularly applies to corrosivity, permeability, softening, premature aging and embrittlement. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 7.62 mm (0.300 inch) or the thickness required for a tank with a design pressure at least equal to 1.5 times the vapor pressure of the lading at 46 C (115 F). Choosing an item from The Office of the Federal Register publishes documents on behalf of Federal agencies but does not have any authority over their programs. B82 Cargo tanks and portable tanks are not authorized. This may be fulfilled by an additional locking device linked to the activator; (4) Each article must be manufactured in such a way as to prevent hazardous projections of the pressure receptacle or parts of the pressure receptacle; (5) Each pressure receptacle must be manufactured from material which will not fragment upon rupture; (6) The design type of the article must be subjected to a fire test. B42 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105J. Interior heating coils are not authorized. b. d. Receptacles containing adsorbed or absorbed ammonia shall meet the following conditions: (1) Receptacles shall be made of a material compatible with ammonia as specified in ISO 11114-1:2012(E) and ISO 11114-1:2012/Amd 1:2017(E) (IBR, see 171.7 of this subchapter); (2) Receptacles and their means of closure shall be hermetically sealed and able to contain the generated ammonia; (3) Each receptacle shall be able to withstand the pressure generated at 85 C (185 F) with a volumetric expansion no greater than 0.1%; (4) Each receptacle shall be fitted with a device that allows for gas evacuation once pressure exceeds 15 bar (1500 kPa) without violent rupture, explosion or projection; and. Symbol Meaning Which is the correct column for hazardous materials? contact the publishing agency. However, sediments remaining in the tank that meet the definition for a hazardous material are subject to the applicable regulations of this subchapter. B85 Cargo tanks must be marked with the name of the lading in accordance with the requirements of 172.302(b). (iv) T75. Terminal protection methods include but are not limited to the following: (i) Securely attaching covers of sufficient strength to protect the terminals; (ii) Packaging the battery in a rigid plastic packaging; or. **Self-reactive materials that are thermally unstable and that There must be no hazardous effects outside the package such as disruption of the package, metal fragments or a receptacle which passes through the packaging.